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Single Bond Energies
Thermochemistry Table
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• Physical Chemistry & Thermodynamics
• Make an Endothermic Reaction
• Endothermic & Exothermic Reactions
• Worked Heats of Formation Problems
• Laws of Thermochemistry
• Worked Enthalpy Change Problems
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• Heats of Formation - Ions
• Heats of Formation - Compounds
• Valences of the Elements
• Electronic Configuration of the Elements
 
 

Knowing the values for bond energy helps us to predict whether a reaction will be exothermic or endothermic. For example, if the bonds in the product molecules are stronger than the bonds of the reactant molecules, then the products are more stable and have a lower energy than the reactants, and the reaction is exothermic. If the reverse is true, then energy (heat) must be absorbed in order for the reaction to occur, making the reaction endothermic. In this case, the products have a higher energy than the reactants. Bond energies may be used to calculate change in enthalpy, DH, for a reaction by applying Hess's Law. DH can be obtained from the bond energies only when all of the reactants and products are gases.

Single Bond Energies (kJ/mol) at 25°C
  H C N O S F Cl Br I
436  414  389  464  339  565  431  368  297 
  347  293  351  259  485  331  276  238 
    159  222  --  272  201  243  -- 
      138  --  184  205  201  201 
        226  285  255  213  -- 
          153  255  255  -- 
Cl              243  218  209 
Br                193  180 
                151 

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